phenol to bakelite
For the making of laminated structures, sheets of paper or fabric were impregnated with the resin in an alcohol solution and then heated under pressure to form tough, rigid assemblies. [7]:44–45[22][25], Phenolic resin products may swell slightly under conditions of extreme humidity or perpetual dampness. [44] Bakelite was also used to make presentation boxes for Breitling watches. When heat and pressure are applied, polymerization transforms the layers into thermosetting industrial laminated plastic. [47][48] Kitchenware made with Bakelite, including canisters and tableware, was promoted for its resistance to heat and to chipping. Good mechanical and impact strength with continuous operating temperature of 250 °F (120 °C). CO. LTD. In recent years the "retro" appeal of old Bakelite products has made them collectible. Some common types include:[24], Bakelite has a number of important properties. Good mechanical and electrical strength. In the 1920s it was widely used in knobs, dials, circuitry panels, and even cabinets for radios, and it was also employed in the electrical systems of automobiles. [4] By controlling the pressure and temperature applied to phenol and formaldehyde, Baekeland produced a hard moldable material that he named "Bakelite," after himself. These and other materials are put through molds which form rods. In 1927 the Bakelite patent expired. [4], Baekeland was already wealthy due to his invention of Velox photographic paper when he began to investigate the reactions of phenol and formaldehyde in his home laboratory. [7], Baekeland filed a substantial number of patents in the area. Bakelite was also very commonly used in making molded grip panels (stocks) on handguns, submachine guns and machineguns, as well as numerous knife handles and "scales" through the first half of the 20th century.[39]. PF resin is formed when molecules of phenol (C. Be on the lookout for your Britannica newsletter to get trusted stories delivered right to your inbox. [51][52] By 1935, it was used in solid-body electric guitars. [11][12] However, the demand for molded plastics led the Bakelite company to concentrate on molding, rather than concentrating on cast solid resins. A hard, infusible, and chemically resistant plastic, Bakelite was based on a chemical combination of phenol and formaldehyde (phenol-formaldehyde resin), two compounds that were derived from coal tar and wood alcohol (methanol), respectively, at that time. Bakelite stock is still manufactured and produced in sheet, rod and tube form for industrial applications in the electronics, power generation and aerospace industries, and under a variety of commercial brand names. It is a thermosetting phenol formaldehyde resin, formed from a condensation reaction of phenol with formaldehyde. We began the production of bakelite powder from 1992. A hard, infusible, and chemically resistant plastic, Bakelite was based on a chemical combination of phenol and formaldehyde (phenol-formaldehyde resin), two compounds that were derived from coal tar and wood alcohol (methanol), respectively, at that time. Experiments with phenolic resins had actually preceded Baekeland’s work, beginning in 1872 with the work of German chemist Adolf von Baeyer, but these trials had succeeded only in producing viscous liquids or brittle solids of no apparent value. This page was last edited on 22 December 2020, at 21:47. "[59], In 1947, Dutch art forger Han van Meegeren was convicted of forgery, after chemist and curator Paul B. Coremans proved that a purported Vermeer contained Bakelite, which van Meegeren had used as a paint hardener. Recommended for intricate high strength parts. Bakelite is made of powdered phenolic resin, which is mixed with sawdust, asbestos or clay, and then pressed into a finished product at a high temperature.
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